NPC Trade: Konikoni City (Only in Sun & Moon)
SOS Encounter: Malie Garden (10%)
Walk: Malie Garden (20%, Only in Ultra Sun & Ultra Moon)
Its base catch rate is 120 out of 255 (higher is easier); the catch rate calculator works out your odds with each ball. For the look, the best colour match is Dive Ball.
Evolution: Poliwag → Poliwhirl (Level 25) → Poliwrath (Water Stone) · Politoed.
Poliwhirl in every game · Pokémon Sun, Moon, Ultra Sun & Ultra Moon interactive map (Alola)